Solution to 1996 Problem 74


We use the formula dS = \delta Q/T. We assume the system has reached thermal equilibrium. This means that the two bodies must have the same temperature. Conservation of energy implies that this temperature must be 300 \mbox{ K}. If the equilibrium temperature were greater than 300 \mbox{ K}, the amount of heat enters the body originally at 100 \mbox{ K} would be greater than the amount of heat that leaves the body originally at 500 \mbox{ K}. If the equilibrium temperature were less than 300 K, the amount of heat that leaves the body originally at 500 \mbox{ K} would be greater than the amount of heat that enters the body originally at 100 \mbox{ K}. Both situations violate conservation of energy (this assumes, of course, that the heat capacity C is a constant). The entropy change of the body originally at 500 \mbox{ K} is
\begin{align*}\int \frac{\delta Q}{T} = \int_{500} ^{300} \frac{m  C dT}{T} = m C \ln(3/5)\end{align*}
The entropy change of the body originally at 100 \mbox{ K} is
\begin{align*}\int \frac{\delta Q}{T} = \int_{100} ^{300} \frac{m  C dT}{T} = m C \ln(3/1)\end{align*}
Therefore, the total entropy change is
\begin{align*}m C \ln(3/5) + m C \ln(3/1) = m C \ln (9/5)\end{align*}
Hence answer (B) is correct.


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